Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
With the ever-increasing demand for plastics, sustainable recycling methods are key necessities. The current plastics industry can manage to recycle only 10% of the 400 million metric tons of plastic produced globally. Waste plastics, in the current infrastructure, land up mostly in landfills. Although a lot of research efforts have been spent on processing and recycling co-mingled mixed plastics, energy-efficient sustainable and scalable routes for plastic upcycling are still lacking. Catalytic valorization of waste plastic feedstock is one of the potential scalable routes for plastic upcycling. Silica-alumina based materials, and zeolites have shown a lot of promise. A major interest lies in restricting catalyst deactivation, and refining product selectivity and yield for such catalytic processes. This article highlights ChemPren technology as a clean energy solution to waste plastic recycling. Co-mingled, mixed plastic feedstock along with spray dried, attrition resistant, ZSM-5 containing catalysts is preprocessed with an extruder to form optimally sized particles and fed into a fluidized bed reactor for short contact times to produce selectively and in high yields ethylenes, propylenes and butylenes. This techno-economic perspective indicates that the ChemPren technology can produce propylene at $0.16 per lb, whereas the current selling price of virgin propylene is $0.54 per lb. This technology can serve as a platform for mixed plastic upcycling, with more advancements necessary in the form of robust and resilient catalysts and reactor operation strategies for tuning product selectivity.more » « less
-
Context. The typically large distances, extinction, and crowding of Galactic supermassive star clusters (stellar clusters more massive than 104M⊙) have so far hampered the identification of their very low mass members, required to extend our understanding of star and planet formation, and early stellar evolution, to the extremely energetic star-forming environment typical of starbursts. This situation has now evolved thanks to theJames WebbSpace Telescope (JWST), and its unmatched resolution and sensitivity in the infrared. Aims. In this paper, the third of the series of the Extended Westerlund 1 and 2 Open Clusters Survey (EWOCS), we present JWST/NIRCam and JWST/MIRI observations of the supermassive star cluster Westerlund 1. These observations are specifically designed to unveil the cluster members down to the brown dwarf mass regime, and to allow us to select and study the protoplane-tary disks in the cluster and to study the mutual feedback between the cluster members and the surrounding environment. Methods. Westerlund 1 was observed as part of JWST GO-1905 for 23.6 hours. The data have been reduced using the JWST calibration pipeline, together with specific tools necessary to remove artifacts, such as the 1 /frandom noise in NIRCam images. Source identification and photometry were performed withDOLPHOT. Results. The MIRI images show a plethora of different features. Diffuse nebular emission is observed around the cluster, which is typically composed of myriads of droplet-like features pointing toward the cluster center or the group of massive stars surrounding the Wolf–Rayet star W72/A. A long pillar is also observed in the northwest. The MIRI images also show resolved shells and outflows surrounding the M-type supergiants W20, W26, W75, and W237, the sgB[e] star W9 and the yellow hypergiant W4. Some of these shells have been observed before at other wavelengths, but never with the level of detail provided by JWST. The color-magnitude diagrams built using the NIRCam photometry show a clear cluster sequence, which is marked in its upper part by the 1828 NIRCam stars with X-ray counterparts. NIRCam observations using the F115W filter have reached the 23.8 mag limit with 50% completeness (roughly corresponding to a 0.06 M0 brown dwarf).more » « lessFree, publicly-accessible full text available January 1, 2026
An official website of the United States government

Full Text Available